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Sains Malaysiana 52(9)(2023):
http://doi.org/10.17576/jsm-2023-5209-19
Photoreforming
of Glycerol Catalyzed by CuO/TiO2 Supported on Hydroxyapatite
(Pembentukan
Semula Gliserol Pemangkin oleh Cuo/Tio2 Disokong pada Hidroksiapatit)
DAMRONG ADAM1, NETNAPID
ONGSUWAN2, & SAOWAPA CHOTISUWAN1,*
1Department of Science, Faculty
of Science and Technology, Prince of Songkla University, Rusamilae, Pattani,
Thailand
2Department of Food Science and
Nutrition, Department of Science, Faculty of Science and Technology, Prince of
Songkla University, Rusamilae, Pattani, Thailand
Diserahkan:
23 Mac 2023/Diterima: 15 Ogos 2023
Abstract
Waste bovine bones can be used as a source to
produce hydroxyapatite (HAp), which is a good organic adsorbent and
used as a support material for metal oxide photocatalysts. In this work, HAp powders were prepared from
calcination of bovine bones at 900 °C for 2 h and used as supporting
material for a TiO2 photocatalyst incorporating CuO. The hexagonal HAp
particles were characterized using Fourier transformed infrared spectroscopy
(FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The
50 wt% TiO2 and 1 wt% CuO/TiO2 supported on HAp photocatalysts
were synthesized by the co-precipitation method and finally calcined at
450 °C for 4 h. The synthesized HAp and catalysts were
characterized by FTIR, XRD, BET surface area analysis, SEM, and transmission
electron microscopy (TEM). The photocatalytic performance
of the synthesized catalysts was performed by photoreforming
of glycerol at room temperature using 100 mL of 0.5 M glycerol solution under
nitrogen atmosphere, irradiating with low-light intensity 20 W Mercury UV lamp
for 7 h. The gaseous products catalyzed by the synthesized catalysts were
analyzed using a gas chromatograph. The maximum
hydrogen gas production from photoreforming of glycerol at this condition was
obtained at 513.7 mmol gcat–1 without carbon dioxide detection
after catalyzing by CuO/TiO2/HAp catalyst.
Keywords: Glycerol; hydroxyapatite;
photoreforming; titania
ABSTRAK
Sisa
tulang lembu boleh digunakan sebagai sumber untuk menghasilkan hidroksiapatit (HAp), yang merupakan penyerap organik yang baik dan digunakan
sebagai bahan sokongan untuk fotokatalis oksida logam. Dalam kertas ini, serbuk HAp disediakan
daripada kalsinasi tulang lembu pada suhu 900 °C selama 2 jam dan digunakan
sebagai bahan sokongan untuk fotokatalis TiO2 yang menggabungkan CuO. Zarah HAp heksagon dicirikan menggunakan
spektroskopi inframerah Fourier berubah (FTIR), pembelahan sinar-X (XRD) dan
mikroskop elektron imbasan (SEM). 50 wt% TiO2 dan 1
wt% CuO/TiO2 yang disokong pada fotokatalis HAp
disintesis oleh kaedah pemendakan bersama
dan akhirnya dikalsinasi pada 450 °C untuk 4 jam. HAp dan pemangkin
yang disintesis dicirikan oleh FTIR, XRD, ANALISIS kawasan permukaan BET, SEM
dan mikroskop elektron penghantaran (TEM). Prestasi
fotokatalisis pemangkin yang disintesis dilakukan dengan pembentukan semula
foto gliserol pada suhu bilik menggunakan 100 mL 0.5 M. Penyelesaian gliserol di bawah atmosfera
nitrogen, mengairi dengan keamatan cahaya rendah 20 W Mercury UV lampu untuk 7
jam. Produk gas yang pemangkin oleh pemangkin
yang disintesis telah dianalisis menggunakan kromatograf gas. Pengeluaran gas
hidrogen maksimum daripada pembentukan semula gliserol dalam keadaan ini
diperoleh pada 513.7 mmol gcat-1 tanpa pengesanan karbon dioksida selepas pemangkin oleh pemangkin CuO/TiO2/HAp.
Kata
kunci: Gliserol; hidroksiapatit; pembentukan semula; titania
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